S23. Electrochemical Reaction of Water-insoluble Organic Droplets in Aqueous Electrolytes Using Acoustic Emulsification(Oral Presentation)

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概要

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• Electrochemical oxidation of water-insoluble amines (n-octylamine and n-decylamine) was successfully accomplished in aqueous electrolytes using acoustic emulsification. Ultrasonication to the water-insoluble organic substrate/aqueous electrolyte mixtures allowed a formation of very stable emulsions having the characteristic of giving narrow monomer droplet size distributions in the submicrometer range in aqueous electrolytes without added surfactants and the smooth electrochemical reaction in the emulsions took place via direct electron transfer between the electrode and the water-insoluble organic droplets. In this kind of electron-transfer system, supporting electrolyte should be dissolved not only in the aqueous phase but also in the organic droplets and contribute to the formation of an electric bilayer inside the droplets.

• 日本ソノケミストリー学会の論文
• 2011-10-15

著者

• Atobe Mahito

  Department Of Electronic Chemistry Tokyo Institute Of Technology

• Nakabayashi Koji

  Department Of Chemistry School Of Science The University Of Tokyo

• Fuchigami Toshio

  Department Of Electronic Chemistry Tokyo Institute Of Technology

• NAKABAYASHI Koji

  Department of Electronic Chemistry, Tokyo Institute of Technology

• Ikari Shintaro

  Department of Electronic Chemistry, Tokyo Institute of Technology

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