Kinetic studies on dehydrogenation reaction of 5,6-dihydro-2,4(1H,3H)-pyrimidinediones in aqueous solution induced by argon arc plasma or hydrogen-oxygen flame.
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概要
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5,6-Dihydro-2,4(1<I>H</I>,3<I>H</I>)-pyrimidinediones underwent dehydrogenation at the 5- and 6-position producing 2,4(1<I>H</I>,3<I>H</I>)-pyrimidinediones in aqueous solution induced by argon arc plasma or flames. From consideration based on the kinetic study of this reaction, it was found that abstraction of a hydrogen atom took place preferentially at the 6-position of the dihydropyrimidinediones.
- 公益社団法人 日本化学会の論文
著者
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Nomoto Shinya
Department Of Chemistry The University Of Tsukuba
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Naraoka Hiroshi
Department Of Chemistry Graduate School Of Science Tokyo Metropolitan University
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Harada Kaoru
Department of Chemistry Faculty of Science Osaka University
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Takasaki Michiaki
Department of Chemistry, The University of Tsukuba
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Naraoka Hiroshi
Department of Chemistry, University of Tsukuba
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