Amination of Carboxylic Acids by Reductive Fixation of Molecular Nitrogen by Glow Discharge Against Aqueous Solution.
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概要
- 論文の詳細を見る
Amination of several carboxylic acids by reductive fixation of molecular nitrogen was achieved by glow discharge against aqueous solution of these carboxylic acids. The yield of the aminated product is the highest in the case of maleic acid among carboxylic acids used. The addition of hydrochloric acid to the reaction mixture enhances the yields of aminated products. This may be caused by the fact that chloride anion is oxidized by hydroxyl radicals to chlorate ion, and the fixation of molecular nitrogen proceeds under relatively reducing conditions.
- 公益社団法人 日本化学会の論文
著者
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Shimoyama Akira
Department Of Chemistry University Of Tsukuba
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Munegumi Toratane
Department Of Industrial Chemistry Oyama National College Of Technology
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Harada Kaoru
Department of Chemistry Faculty of Science Osaka University
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Takasaki Michiaki
Department of Chemistry, The University of Tsukuba
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Igari Shun-ichiro
Department of Chemistry, University of Tsukuba
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