ESR spectroscopic study of triphenylmethyl-substituted thioaminyl radicals: N-(triphenylmethylthio)alkylaminyls and -arylaminyls.
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概要
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The title radicals, generated by hydrogen-atom abstraction from the corresponding <I>N</I>-(triphenylmethylthio)alkylamines and -arylamines, have been studied by means of ESR spectroscopy. The alkylaminyls were transient in solution at room temperature, while the arylaminyls persisted for a long period under the same conditions. The ESR parameters are discussed by comparing them with those for structurally related aminyls.
- 公益社団法人 日本化学会の論文
著者
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MIURA Yozo
Department of Appleid Chemistry, Faculty of Engineering, Osaka City University
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MIURA Yozo
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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Isogai Mamoru
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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Kinoshita Masayoshi
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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