An ESR study of N,N-bis(arylthio)aminyls. 33S hyperfine splittings.
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概要
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In the ESR spectra of <I>N</I>,<I>N</I>-bis(phenylthio)-, <I>N</I>,<I>N</I>-bis(phenyl-<I>d</I><SUB>5</SUB>-thio)-, and <I>N</I>,<I>N</I>-bis(3,5-dichlorophenylthio)aminyls, <SUP>33</SUP>S hyperfine splittings were detected. The spin densities in the aminyls were calculated by using the HMO calculations with and without McLachlan's correction, and the results were compared with the values derived from the <SUP>1</SUP>H, <SUP>14</SUP>N, and <SUP>33</SUP>S hyperfine splittings by use of the relationship <I>a</I>=<I>Q</I>ρ.
著者
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MIURA Yozo
Department of Appleid Chemistry, Faculty of Engineering, Osaka City University
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Kinoshita Masayoshi
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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