A three-component reaction of isocyanides with halogens and cyclic ethers.

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概要

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• In the presence of a Lewis-acid catalyst, such as HgCl<SUB>2</SUB> or ZnCl<SUB>2</SUB>, cyclohexyl isocyanide reacted with chlorine and tetrahydrofuran to give, after hydrolysis, 4-chlorobutyl cyclohexylcarbamate in a fair yield. When one of the reactants was replaced by another isocyanide, bromine, or another cyclic ether, the reactions proceeded similarly, but the corresponding carbamate yields were rather poor.

• 公益社団法人 日本化学会の論文

著者

• Tanimoto Shigeo

  Institute For Chemical Research Kyoto University Uji

• Okano Masaya

  Institute for Chemical Research, Kyoto University

• Wada Yasuo

  Institute for Chemical Research, Kyoto University

• Yamazaki Takeshi

  Institute for Chemical Research, Kyoto University

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