Oxidation of olefins with thallium(III) acetate in diols.
スポンサーリンク
概要
- 論文の詳細を見る
The oxidation of styrene, α- and β-methylstyrene, and 1-octene with thallium(III) acetate in diols, HO(CH<SUB>2</SUB>)<I><SUB>n</SUB></I>OH (<I>n</I>=2, 3, and 4), has been investigated. From styrene the derivatives of 1,3-dioxolane, 1,3-dioxane, and 1,3-dioxepane were mainly obtained for <I>n</I>=2, 3, and 4 respectively, while the reaction of 1-octene in 1,2-ethanediol afforded 1-acetoxy-2-(2-hydroxyethoxy)octane as the main product. A new alkoxythallate of styrene, C<SUB>6</SUB>H<SUB>5</SUB>CH(OCH<SUB>2</SUB>CH<SUB>2</SUB>OH)CH<SUB>2</SUB>Tl(OAc)<SUB>2</SUB>, has been isolated under milder conditions.
- 公益社団法人 日本化学会の論文
著者
-
Toshimitsu Akio
Institute For Chemical Research Kyoto University
-
Okano Masaya
Institute for Chemical Research, Kyoto University
-
Uemura Sakae
Institute for Chemical Research, Kyoto University
-
Miyoshi Haruo
Institute for Chemical Research, Kyoto University
関連論文
- Stereochemistry of the Intramolecular Substitution of Phnylselenonyl Group by Nitrogen Atom in Amide. Inversion of Configuration
- Nucleophilic Addition of a Divalent Silicon Species Bearing the 8-Dimethylamino-1-naphthyl Group to Diphenylacetylenes to Form the 1-Amino-1-silaphenalene Skeleton
- Trimerization of a Divalent Silicon Species Bearing the 8-Dimethylamino-1-naphthyl Group Accompanied by the Migration of Methyl and Dimethylamino Groups
- Wurtz - type Coupling Reaction of Pseudo - pentacoordinate Halodisilanes Using Magnesium : Enhanced Reactivity of the Silicon - Halogen Bond by Intramolecular Amine - Coordination to Silicon
- Intramolecular Cyclization Reaction via a Sterically Protected Episelenonium Ion Intermediate
- Enhanced Leaving Ability of Methoxy Group and Retarded Deprotonation on the Carbon Atom Linked to the 1-Position of 8-Phosphino- or 8-Amino-naphthalene
- Asymmetric Carbon-Carbon Bond Formations by the Reaction of "Chiral Episulfonium Ions" with Enol Silyl Ethers
- The formylation of an aromatic nucleus by the use of 2-ethoxy-1,3-dithiolane.
- The reactions of the 1,2-ethanediylbis(trithiocarbonic acid) dianion with several electrophilic reagents.
- The reactions of olefins with chloromethoxymethane or dimethoxymethane in nitriles.
- Synthesis and lithiation of 2-alkylthio- and 2-arylthio-1,3-dithiolanes.
- Selenium and tellurium tetrachlorides as reagents for the conversion of alcohols to alkyl chlorides and tellurium tetrachloride as a Lewis acid catalyst for aromatic alkylation.
- Chlorination of acetylenes with sulfuryl chloride.
- The formation of vinyl sulfides by the cleavage of the carbon-sulfur bond in dithioacetals with CuCl2.
- The Chlorination of Cyclooctadiene with Cupric Chloride in Acetonitrile Containing Lithium Chloride
- The reaction of alkyl halides with mercury(II) and potassium thioacetates and selenocyanates.
- Oxidation of Isocyanides by Hg(II), Tl(III), and Pb(IV) Acetates
- Explosion during the Preparation of Ethylphenyl Thallic Acetate Perchlorate
- A convenient method for the introduction of 1,3-dithiolan-2-yl group into active methylene compounds.
- The chlorination of norbornene by metal chlorides and the product isomerization.
- O-methylation of aromatic (E)-oximes by dimethylsulfonium methylide.
- Selenocyanatodethallation in Organothallium(III) Compounds
- Amidoselenation of Olefins Using p-Toluenesulfonamide as a Nitrogen Nucleophile.
- The chlorination of norbornadiene by various chlorinating agents.
- A three-component reaction of isocyanides with halogens and cyclic ethers.
- Phenyl- and tolylthallium(III) bis(trichloroacetate)s; Preparation and reactions.
- Ring-opening reaction of oxiranes, oxetanes, and tetrahydropyran by mercury(II) salts and alkyl halides.
- The Reaction of Arylthallium(III) Compounds with Copper(II) and (I) Thiocyanates
- Oxidation of olefins with thallium(III) acetate in diols.