The chlorination of norbornadiene by various chlorinating agents.
スポンサーリンク
概要
- 論文の詳細を見る
The chlorination of norbornadiene by CuCl<SUB>2</SUB>, TlCl<SUB>3</SUB>·4H<SUB>2</SUB>O, SbCl<SUB>5</SUB>, SeCl<SUB>4</SUB>, and VCl<SUB>4</SUB> in CCl<SUB>4</SUB> or CH<SUB>3</SUB>-CN afforded mainly <I>trans</I>-3,5-(<B>1</B>) and <I>exo</I>-<I>cis</I>-3,5-dichloronortricyclene (<B>2</B>). In the reaction with PbCl<SUB>4</SUB>, Cl<SUB>2</SUB>, SO<SUB>2</SUB>Cl<SUB>2</SUB>, and PCl<SUB>5</SUB>, appreciable amounts of <I>exo</I>-5-<I>syn</I>-7-(<B>3</B>) and/or <I>exo</I>-<I>cis</I>-5,6-dichloronorbornene (<B>4</B>) were obtained besides <B>1</B> and <B>2</B>.
- 公益社団法人 日本化学会の論文
著者
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Okano Masaya
Institute for Chemical Research, Kyoto University
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Uemura Sakae
Institute for Chemical Research, Kyoto University
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Onoe Akira
Institute for Chemical Research, Kyoto University
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