The reactions of olefins with chloromethoxymethane or dimethoxymethane in nitriles.

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概要

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• The Lewis acid-catalyzed reactions of olefins with chloromethoxymethane (CM) or dimethoxymethane (DM) and aliphatic or aromatic nitriles afforded the 1 : 1 : 1 adducts and/or their hydrolysis products in various yields, together with the 1 : 1 olefin–CM (or DM) adducts. AlCl<SUB>3</SUB>, FeCl<SUB>3</SUB>, ZnCl<SUB>2</SUB>, and SnCl<SUB>4</SUB> were effective catalysts for the reaction with CM, whereas BF<SUB>3</SUB> and SnCl<SUB>4</SUB> were effective for that with DM. In the case of cyclohexene, the addition proceeded in the <I>trans</I>-manner; <I>i.e.</I>, the methoxymethyl group and the nitrile molecule were added to the olefin from opposite sides.

• 公益社団法人 日本化学会の論文

著者

• Tanimoto Shigeo

  Institute For Chemical Research Kyoto University Uji

• Okano Masaya

  Institute for Chemical Research, Kyoto University

• Nishiura Kazuo

  Institute for Chemical Research, Kyoto University

• Wada Yasuo

  Institute for Chemical Research, Kyoto University

• Yamazaki Takeshi

  Institute for Chemical Research, Kyoto University

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