Oxidation of Isocyanides by Hg(II), Tl(III), and Pb(IV) Acetates

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概要

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• Isocyanides were oxidized to isocyanates in acetic acid in the presence of Hg(II), Tl(III), or Pb(IV) acetate through acetoxymetallation. The reaction of an isocyanide with Tl(III) acetate in various alcohols gave the corresponding carbamates in good yields.

• 公益社団法人 日本化学会の論文

著者

• Okano Masaya

  Institute for Chemical Research, Kyoto University

• Uemura Sakae

  Institute for Chemical Research, Kyoto University

• Kido Hiroshi

  Institute for Chemical Research, Kyoto University

• Tanaka Sakuya

  Institute for Chemical Research, Kyoto University

関連論文

• P-2 STUDY OF THE LETHAL VENOM FROM THE SHORT-TAILED SHREW Blarina brevicauda
• The formylation of an aromatic nucleus by the use of 2-ethoxy-1,3-dithiolane.
• The reactions of the 1,2-ethanediylbis(trithiocarbonic acid) dianion with several electrophilic reagents.
• The reactions of olefins with chloromethoxymethane or dimethoxymethane in nitriles.
• Synthesis and lithiation of 2-alkylthio- and 2-arylthio-1,3-dithiolanes.
• Selenium and tellurium tetrachlorides as reagents for the conversion of alcohols to alkyl chlorides and tellurium tetrachloride as a Lewis acid catalyst for aromatic alkylation.
• Chlorination of acetylenes with sulfuryl chloride.
• The formation of vinyl sulfides by the cleavage of the carbon-sulfur bond in dithioacetals with CuCl2.
• The Chlorination of Cyclooctadiene with Cupric Chloride in Acetonitrile Containing Lithium Chloride
• The reaction of alkyl halides with mercury(II) and potassium thioacetates and selenocyanates.
• Oxidation of Isocyanides by Hg(II), Tl(III), and Pb(IV) Acetates
• Explosion during the Preparation of Ethylphenyl Thallic Acetate Perchlorate
• A convenient method for the introduction of 1,3-dithiolan-2-yl group into active methylene compounds.
• The chlorination of norbornene by metal chlorides and the product isomerization.
• O-methylation of aromatic (E)-oximes by dimethylsulfonium methylide.
• Selenocyanatodethallation in Organothallium(III) Compounds
• The chlorination of norbornadiene by various chlorinating agents.
• A three-component reaction of isocyanides with halogens and cyclic ethers.
• Phenyl- and tolylthallium(III) bis(trichloroacetate)s; Preparation and reactions.
• Ring-opening reaction of oxiranes, oxetanes, and tetrahydropyran by mercury(II) salts and alkyl halides.
• The Reaction of Arylthallium(III) Compounds with Copper(II) and (I) Thiocyanates
• Oxidation of olefins with thallium(III) acetate in diols.

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