The Reaction of Arylthallium(III) Compounds with Copper(II) and (I) Thiocyanates
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概要
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Arylthallium(III) acetate perchlorates reacted with copper(II) thiocyanate to afford aryl thiocyanates in various solvents. The Cu(I) salt was found to be less effective for the thiocyanation. The choice of solvent and the addition of potassium thiocyanate had a significant effect on the yield of aryl thiocyanates. The reaction with the mixture of copper(II) and potassium thiocyanates (1: 1) in dioxane showed the best result. Electron-releasing groups in the aromatic ring accelerated hydrodethallation, yielding aromatic hydrocarbons with a depression of the thiocyanate formation.
- 公益社団法人 日本化学会の論文
著者
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Okano Masaya
Institute for Chemical Research, Kyoto University
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Uemura Sakae
Institute for Chemical Research, Kyoto University
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Ichikawa Katsuhiko
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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Uchida Satoru
Institute for Chemical Research, Kyoto University
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