Asymmetric Synthesis in the Oxymercuration Reaction Using Optically Active Mercuric Salts
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概要
- 論文の詳細を見る
The oxymercuration-demercuration of styrene with optically active mercuric tartrate, 2-phenylpropionate, mandelate, camphorate, menthoxyacetate, and monomethyl tartrate resulted in a partial asymmetric synthesis of 1-phenylethanol. When mercuric tartrate was used, exceptionally high optical yields (25–32%) were observed. The mechanisms for the asymmetric synthesis are discussed.
- 公益社団法人 日本化学会の論文
著者
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Sugita Toshio
Department Of Electrical Engineering Science University Of Tokyo
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Itoh Osamu
Department Of Internal Medicine Ii Fukushima Medical College
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Ichikawa Katsuhiko
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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Yamasaki Yasuo
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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Itoh Osamu
Department of Chemistry, The University of Tsukuba
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Itoh Osamu
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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