The lithium diisopropylamide-induced fragmentation of 2,2-diphenyl-1,3-dithiolane S-oxide and several 2,2-diaryl-1,3-dithiolane S,S'-dioxides.
スポンサーリンク
概要
- 論文の詳細を見る
The reaction of 2,2-diphenyl-1,3-dithiolane <I>S</I>-oxide with lithium diisopropylamide results in fragmentation to thiobenzophenone followed by further conversion leading to alkyl diphenylmethyl sulfide on trapping with alkyl halide. The reaction of 2,2-diaryl-1,3-dithiolane <I>S</I>,<I>S</I>′-dioxides with lithium diisopropylamide proceeded smoothly to afford 1,1-diaryl-<I>N</I>,<I>N</I>-diisopropylmethanesulfinamides in moderate yields via the intermediate diaryl thioketone <I>S</I>-oxides.
- 公益社団法人 日本化学会の論文
著者
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Inoue Yoshihiko
Institute For Chemical Research Kyoto University
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Tanimoto Shigeo
Institute For Chemical Research Kyoto University Uji
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Oida Tatsuo
Institute for Chemical Research, Kyoto University
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