The oxidative amination of tropone and tropolone.
スポンサーリンク
概要
- 論文の詳細を見る
The reaction of tropone with aniline, <I>p</I>-toluidine, <I>p</I>-anisidine, and <I>p</I>-chloroaniline in the presence of copper(II) acetate gave 2-arylaminotropones and 2-arylamino-<I>N</I>-aryltroponeimines. However, when <I>o</I>-toluidine and <I>o</I>-anisidine were used, only the corresponding 2-arylaminotropones were obtained. The reaction of tropolone with methylamine, ethylamine, and isopropylamine afforded 3-aminotropolone derivatives, while the reaction with dimethylamine, pyrrolidine, and morpholine gave 3- and 5-aminotropolone derivatives, the latter being minor products.
- 公益社団法人 日本化学会の論文
著者
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Maki Yuji
Department Of Biological And Material Chemistry Faculty Of Science Yamagata University
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Sato Kazuo
Department Of Mechanical Engineering Ii Shibaura Institute Of Technology
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Kikuchi Katsuo
Department of Chemistry Faculty of Science Tohoku University
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Kikuchi Katsuo
Department of Chemistry, Faculty of Science, Yamagata University
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Sato Kazuo
Department of Chemistry, Faculty of Science, Yamagata University
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