The oxidative amination of diethyl 2-hydroxyazulene-1,3-dicarboxylate and cycloheptimidazol-2(1H)-one.

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概要

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• The reaction of diethyl 2-hydroxyazulene-1,3-dicarboxylate with morpholine, pyrrolidine, piperidine, and dimethylamine in the presence of copper(II) acetate gave the respective 6-aminoazulene derivatives. Similarly, the reaction of cycloheptimidazol-2(1<I>H</I>)-one with morpholine gave the 6-ami-nocycloheptimidazole derivative, while the reaction with pyrrolidine gave the 4-(or 5-)aminocycloheptimidazole derivative.

• 公益社団法人 日本化学会の論文

著者

• Maki Yuji

  Department Of Biological And Material Chemistry Faculty Of Science Yamagata University

• Kikuchi Katsuo

  Department of Chemistry Faculty of Science Tohoku University

• Saito Noriyuki

  Department of Chemistry, Faculty of Science, Yamagata University

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