Visible Circular Dichroism of Lutein Acquired on Dispersion in an Aqueous Solution in the Presence of a Limited Amount of Sodium Dodecyl Sulfate and a Dramatic Change of the CD Spectrum with Concentration of the Surfactant

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Lutein, one of the most common carotenoids, has been believed to be optically inactive in the visible region. Lutein was found, however, to acquire a very strong circular dichroic (CD) activity in this region when dispersed in an aqueous solution in the presence of sodium dodecyl sulfate (SDS). The CD spectrum of lutein had positive and negative extrema before and behind a crossover at about 390 nm, respectively. The signs of the extrema were inverted when the amount of SDS was increased. Further addition of SDS destroyed the CD activity. These phenomena are suggested to reflect a sequence of events, namely; 1) the formation of a helical assembly of the lutein molecules; 2) a wholesale structural change of the assembly resulting in the inversion of its chirality, and 3) the breakdown of the assembly followed by the inclusion of the lutein molecules into SDS micelles.
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