Kinetic Studies of the Reaction between Sodium Dodecyl Sulfate and Pinacyanol Chloride
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概要
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Below the critical micelle concentration, a kinetic study of the aggregate formation reaction of sodium dodecyl sulfate and pinacyanol chloride was made by means of a stopped-flow system combined with a rapid scanning spectrophotometer. The process involves the following four steps and a precipitate whose composition ratio was dodecyl sulfate : pinacyanol= 1 : 1 was obtained as the final product:<BR>(<U>Remark: Graphics omitted.</U>)<BR>where D and S are the dye and detergent molecules respectively. The forward rate constants have been calculated to be 6×10<SUP>5</SUP> (M s)<SUP>−1</SUP> for [S]<SUB>0</SUB>=0.05–0.1 mM in the second step and 1.2×10<SUP>2</SUP>–3.9×10<SUP>−3</SUP> s<SUP>−1</SUP> for [S]<SUB>0</SUB>=0.05–1.0 mM in the third step.
- 公益社団法人 日本化学会の論文
著者
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Takeda Kunio
Department of Applied Chemistry and Biotechnology, Okayama Univ. of Science
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Takeda Kunio
Department of Chemistry, Faculty of Science, Hiroshima University
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Tatsumoto Nobuhide
Department of Chemistry, Faculty of Science, Hiroshima University
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Isshiki Shunji
Department of Chemistry, Faculty of Science, Hiroshima University
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Yasunaga Tatsuya
Department of Chemistry, Faculty of Science, Hiroshima University
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