Kinetic studies of Co(II)-malonate, malate, and glycolate complex-formation reactions in aqueous solutions by the pressure-shock method.
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概要
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A pressure-shock apparatus applicable for the kinetic studies of rapid reactions in solution was constructed and used to study Co(II)–carboxylate complex-formation reactions. The chelate complex-formation reaction was interpreted in terms of a step-by-step mechanism, and the rate constants were obtained. The chelate-ring closing-and-opening process was revealed to be the rate-determining step.
- 公益社団法人 日本化学会の論文
著者
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Harada Shoji
Department Mechanical Engineering Kyushu Institute Of Technology
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Yasunaga Tatsuya
Department of Chemistry, Faculty of Science, Hiroshima University
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Kawasawa Masuo
Department of Chemistry, Faculty of Science, Hiroshima University
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