Kinetic Studies of the Nickel Phthalate Complex Formation in Solution by the Pressure-jump Method
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概要
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The rate constants of the complex formation and the dissociation of the nickel phthalate (<I>o</I>-phthalate) complex have been determined by the pressure-jump method. The thermodynamic parameters of the reaction were obtained from studies at various temperatures between 10 and 30°C. Upon a comparison of the data on the nickel complexes of the succinate, adipate, maleate, and phthalate, no systematic relationship between the nature of the ligands and the kinetic values has been found; this can be ascribed to the monodentated form of these complexes. The rate-determining step is the loss of the water molecule from the inner-coordination sphere of the nickel ion when the monodentated complex is formed.
- 公益社団法人 日本化学会の論文
著者
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Tanabe Hideyuki
Department Of Biosystems Science School Of Advanced Sciences The Graduate University For Advanced St
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Harada Shoji
Department Mechanical Engineering Kyushu Institute Of Technology
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Yasunaga Tatsuya
Department of Chemistry, Faculty of Science, Hiroshima University
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Tanabe Hideyuki
Department of Chemistry, Faculty of Science, Hiroshima University
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