The Role of Proton-Proton Interaction in NH_4H_2PO_4-Type Crystals(Condensed matter: electronic structure and electrical, magnetic, and optical properties)

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概要

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• The interaction between the protons on the nearby hydrogen bonds in NH_4H_2PO_4 (ADP)-type crystals, called the Ishibashi interaction, was analyzed to derive theoretically, i.e., not in an ad hoc way, the effective dipole-dipole interaction between PO_4 radicals, which plays a substantial role in phase transitions. It turns out that at low temperatures the ADP-type antiferroelectric phase is stabilized if the Ishibashi interaction is repulsive, while the monoclinic ferroelectric phase is stabilized otherwise.

• 社団法人日本物理学会の論文
• 2009-01-15

著者

• Iwata Makoto

  Department Of Applied Physics School Of Engineering Nagoya University

• Ishibashi Yoshihiro

  Department Of Applied Physics Graduate School Of Engineering Nagoya University

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