ディーゼル燃料の熱分解成分を用いた拡散火炎中のすす前駆体およびPMの生成(熱工学,内燃機関,動力など)

概要

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Experimental work was performed to investigate formation of soot precursor and PM in diesel combustion process using a flow reactor and a laminar co-flow diffusion burner. Thermally decomposed aliphatic diesel fuel produced in the flow reactor was supplied directly to the burner as fuel. Measurements were conducted in the flow reactor, in the flame, and the exhaust for light hydrocarbons, low molecular weight aromatics, PAHs, soot precursor, and PM. Results show that many PAHs ranging from two to five-member ring are already formed as well as light hydrocarbon such as C_2H_4, C_2H_2 and CH_4 during pyrolysis in the flow reactor. Exhaust PM is subject to be formed when abundant C_2H_2, Benzene, PAHs are produced during high temperature thermal decomposition of aliphatic diesel fuel, and the structure of PM has long chain-like aggregation. Measured fluorescence spectrometry indicates 464nm peak. This peak is caused by soot precursor, which is in the SOF extracted from PM.
社団法人日本機械学会の論文
2007-01-25