The Origin of the Internal Rotation Barrier of Borane Compounds
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概要
- 論文の詳細を見る
The origin of the rotational barriers in borane molecular complexes, H_3N-BH_3,H_3N-BF_3,(CH_3)_3N-BH_3,(CH_3)_3N-BF_3 and (CH_3)_3N-B(CH_3)_3,was shown to be the exchange repulsion by ab initio closed shell LCAO MO SCF calculations. The substituent effects of methyl groups and fluorines on the rotational barrier were attributed to the changes of the exchange repulsion.
- 公益社団法人日本薬学会の論文
- 1979-12-25
著者
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梅山 秀明
School Of Pharmaceutical Sciences Kitasato University
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松崎 尹雄
Central Research Laboratories, Mitsubishi Chemical Industries Ltd.
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松崎 尹雄
Central Research Laboratories Mitsubishi Chemical Industries Ltd.
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