Stereochemistry of Steroid containing Aromatic A-Ring. I. Reaction of 9 (11)-Dehydroestrone.
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概要
- 論文の詳細を見る
Bromination of 3-methoxy-9 (11)-dehydroestrone (II) gave equilenin methylether (IV). Hydroxybromination of 3-acetoxy-9 (11)-dehydrostrone (III) with N-bromosuccinimide in the presence of perchloric acid afforded a bromohydrin (VI), whose structure was assigned 3,9α-dihydroxy-11β-bromoestra-1,3,5 (10)-trien-17-one 3-acetate, on the basis of the resistance of hydroxyl group to acetylation and oxidation, and by leading to 9α, 11α-epoxide (VII) and triol (IX).
- 社団法人日本薬学会の論文
- 1963-08-25
著者
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津田 恭介
Kyoritsu Colledge of Pharmcy
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津田 恭介
東京大学:日本学士院:共立薬科大学
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野副 重男
Institute Of Applied Microbiology The University Of Tokyo:(present Address)pharmaceutical Institute
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岡田 泰
Process Development Laboratories Sankyo Co. Ltd.
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野副 重男
The Institute of Applied Microbiology, University of Tokyo
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岡田 泰
the Shinagawa Plant, Sankyo Co., Ltd.
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