Lewis Acid-Promoted Nitroolefination of Enol Silyl Ethers via an Addition Elimination Process
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概要
- 論文の詳細を見る
Lewis acid-promoted nitroolefination of enol silyl ethers has been developed. Enol ethers 1,4,5,and 6 derived from lactones and lactams furnished nitroolefines 2,7,8,and 9,respectively in 60-99% yields by the treatment with 3 in the presence of Lewis acids. Asymmetric nitroolefination of 5a and 6a with 12 gave 8a and 9a in 75% and 73% ee, respectively.
- 公益社団法人日本薬学会の論文
- 1999-03-15
著者
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Kawabata Takeo
Institute For Chemical Research Kyoto University
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FUJI KAORU
Institute for Chemical Research, Kyoto University
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Ohnishi H
Institute For Chemical Research Kyoto University
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Ohnishi Hiroshi
Manufacturing Engineering Center Mitsubishi Electric Corporation
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Ohnishi Hiroshi
Manufacturing Development Laboratory Mitsubishi Electric Corp.
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Chen Ji-jun
Institute For Chemical Research Kyoto University
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Fuji Kaoru
Institute For Chemical Research Kyoto University
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OHNISHI Hiroshi
Institute for Chemical Research, Kyoto University
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SHANG Muhong
Institute for Chemical Research, Kyoto University
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Shang Muhong
Institute For Chemical Research Kyoto University
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