Structural Studies on Superionic Glass AgI-Ag_2O-MoO_3
スポンサーリンク
概要
- 論文の詳細を見る
Superionic conducting glass of the mole percent 60% Ag I-20% Ag. O-20% Mob.was prepared by rapid quenching from the melt. EXAFS and X-ray RDF studies indicate the presence of strong Ag-I interactions with r...=2.S7 A. Two Ag-0 interaclions whose distances differ by 0.38 A are also indicated. X-Ray RDF studies alsoyield r,. .=2. 1 A and the coordination number of oxygen around Mo, n..-.=5.7. Amodel is proposed which consists of a three dimensional network of distorted Mob.octahedra, which are 6, 4, and 2-corner shared leading to large channels in the structure. The Ag" tons form bonds and secondary interactions with both non-bridgingand bridging oxygen atoms in the network. The I tons surround the Ag" tons in thevoids created by the glass network. The results show that Ag" and I tons are highlydispersed in the glass network and cluster formation was not found as proposed byearlier workers.
- 社団法人日本物理学会の論文
- 1990-04-15
著者
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Nomura Masao
Institute Of Physics College Of Arts And Sciences University Of Tokyo
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OHTAKI Hitoshi
Coordination Chemistry Laboratories, Institute for Molecular Science
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Yamaguchi Tomohiko
Department Of Chemical Systems National Institute Of Materials And Chemical Research (nimc)
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YAMAGUCHI Toshio
Department of Physics, Tokyo Women's Medical University
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Nomura Mitsuhiro
Institute Of Physics University Of Tsukuba:(present Address)fuji Electric Co. Ltd.
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Tsuyoshi Yamaguchi
Faculty Of Engineering Shizuoka University
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Ohtaki H
Coordination Chemistry Laboratories Institute For Molecular Science
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Ohtaki Hitoshi
Coordination Chemistry Laboratories Institute For Molecular Science
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Nomura Masaharu
Photon Factory High Energy Accelerator Research Organization (kek)
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Seshasayee M.
Department of Physics, Indian Institute of Technology
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Seshasayee M.
Department Of Physics Indian Institute Of Technology
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Yamaguchi Toshio
Department Of Chemistry Faculty Of Science Fukuoka University
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Rajalakshmi A.
Department of Physics,Indian Institute fo Technology,Madras,India
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Yamaguchi Toshio
Department of Chemical Engineering, Tokyo University of Agriculture and Technology
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