Quadrupolar Relaxation of ^<27>Al in Aqueous Solution.III.Discussion on Motions of Hydration Water Molecules
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概要
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The chemical potential for the complex consisting of the water molecules co-ordinated to AN"" in water is discussed. The use of the data obtained in aprevious paper Part II [A. Takahashi: J. Phys. Soc. Japan 43 (1977) 976.1 for therate constants for the motions of the hydration water molecules leads to a reason-able conclusion that when one water molecule in the second layer in the complextransfers to the adjacent equilibrium position in the solvent water, the number ofthe hydrogen bond between this molecule and the solvent water molecule increasesby one bond, which forms a momentary stable state in the system. This conclusionconfirms that several approximations made in Part II for the rate constants ofthe molecular motions are valid.
- 社団法人日本物理学会の論文
- 1978-06-15
著者
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Takahashi Akira
Department Of Advanced Materials Science And Engineering Faculty Of Engineering Yamaguchi University
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Takahashi Akira
Department of Physics,Faculty of Technology,Gunma University
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