Uniaxial Stress-Effect on the One-Dimensional Band Structure of [Pt(en)_2][Pt(en)_2Cl_2](ClO_4)_4 (en=ethylenediamine)

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概要

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• Piezoreflectance spectra of quasi-one-dimensional [Pt(an).1 [Pt(en).Cl.](CIO.).crystals have been measured under a uniaxial stress along the chain axis, in thephoton energy range from 1.5 eV to 8 eV. Under a compressive stress, a charge-transfer transition between platinum d.z bands shifts to lower eraergies, whereas transi-lions from halogen p. bands to a platinum d.z band shift to higher energies.Moreover, oscillator strength of the charge-transfer transition increases. These resultsyield a stress-dependence of band parameters in the one-dintensional d.x-p. bandswhich is well explained by the band scheme obtained by the tight-binding approximalion.

• 社団法人日本物理学会の論文
• 1987-03-15

著者

• YAMADA Akio

  Institute of Physics,University of Tsukuba

• Fukutani Hirohito

  Institute Of Physics University Of Tsukuba

• Fukutani Hirohito

  Institute Of Physics College Of General Education University Of Tokyo

• TANAKA Masatoshi

  Laboratory of Applied Physics, Faculty of Engineering, Yokohama National University

• Kurita Susumu

  Laboratory Of Applied Physics Faculty Of Engineering Yokohama National University

• KANEKO Wakahiko

  Laboratory of Applied Physics,Faculty of Engineering,Yokohama National University

• Kaneko Wakahiko

  Laboratory Of Applied Physics Faculty Of Engineering Yokohama National University:nec Corporation

• Tanaka Masatoshi

  Laboratory Of Applied Physics Faculty Of Engineering Ykohama National University

• Yamada Akio

  Institute Of Physics University Of Tsukuba:fujitsu Ltd.

• Tanaka Masatoshi

  Laboratory Of Applied Physics Faculty Of Engineering Yokohama National University

• Yamada Akio

  Institute Of Physics University Of Tsukuba:fujitsu Co. Ltd.

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