Anomalous g-Anisotropy in the ESR Signals of Halogen-Doped AlPcF Thin Films
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概要
- 論文の詳細を見る
Iodine and bromine doped fluoro-aluminum polymer phthalocyanine (AlPcF) thin films are studied by electron spin resonance (ESR). An anomalous g-anisotropy is observed in the ESR spectra of the AlPcF-I_<0.1> and the AlPcF-Br_<0.3> films in which the resonance frequencies of the spins are averaged to the mean value corresponding to g=(g_<⊥>+g_<⫽>)/2. The mechanism of the averaging is the spin diffusion along the string-like winding crystallite caused by the exchange interaction. The films after heat treatment do not involve the averaging, and their ESR line widths have the angle dependence of Γ=Γ0+Γ_1(1+cos^2θ), indicating that the exchange interaction is three dimensional. Both the I-doped and the Br-doped films with and without the heat treatment exhibit 3D-antiferromagnetic transition at around 200 K.
- 社団法人日本物理学会の論文
- 1994-07-15
著者
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Ito Takashi
Department Of Physics University Of Tokyo
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Takeuchi J
Department Of Materials Science Shimane University
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Takeuchi J
Department Of Physics Faculty Of Science Shimane University
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TAKEUCHI Jun
Department of Materials Science, Shimane University
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Takeuchi J
Faculty Of Pharmaceutical Sciences Osaka University
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HIROMITSU Ichiro
Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane Univer
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Ito Takashi
Department Of Chemistry School Of Science The University Of Tokyo
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Ito T
National Inst. Advanced Industrial Sci. And Technol. Ibaraki
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Ohkubo Shinobu
Department of Physics, Faculty of Science, Shimane University
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Ohkubo Shinobu
Department Of Physics Faculty Of Science Shimane University
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Hiromitsu I
Department Of Material Science Interdisciplinary Faculty Of Science And Engineering Shimane Universi
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Hiromitsu Ichiro
Department Of Material Science Shimane University
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Takeuchi Jun
Department Of Material Science Shimane University
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Takeuchi Jun
Department Of Chemical Science And Technology Faculty Of Engineering Kyushu University
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ITO Takashi
Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University
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