The Structure of Pd Complexes of 2-(N-methylthiocarbamoyl) amino-4-methyl-thiazole and 2-(N, N-dimethylthiocarbamoyl) amino-4-methylthiazole
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概要
- 論文の詳細を見る
2-(N-methylthiocarbamoyl) amino-4-methylthiazole (1a) forms a complex quickly with Pd^<2+> at room temperature and pH 2,however, it forms both unstable red complex (B) and stable yellow complex (A) depending upon the molar ratio between the ligand (1a) and Pd^<2+>. The complex (B) changes to the stable complex (A) instantly when (B) contacts with a base or (1a) is added to a chloroform solution of (B). On the other hand, 2-(N, N-dimethylthiocarbamoyl) amino-4-methylthiazole (1a) gives only the stable yellow complex (C) under the same condition. The proposed structures for the complex (A), (B) and (C) are reported.
- 共立薬科大学の論文
著者
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与田 玲子
共立薬科大学
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山本 有一
Kyoritsu College of Pharmacy
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村上 悠紀雄
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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