<一般論文>メタクリル酸とそのn-アルキルエステル類との共重合反応性
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概要
- 論文の詳細を見る
メタクリル酸(MAA)とそのn-アルキルエステル類(RMA)との共重合反応性を調べた結果, ベンゼン中の反応においてRMAのアルキル鎖の増長に伴うモノマー反応性比の大きな変化が認められたが, カルボソ酸中の反応においてはその変化は僅かであった。モノマー反応性比に対するアルキル鎖長の影響およびその溶媒効果の特徴, さらに重合成長反応性に対する水素結合の影響についての分子軌道計算結果を用いた摂動エネルギーによる評価より, モノマー反応性比に対するn-アルキル鎖の立体的影響は小さいこと, また, 実験結果におけるモノマー反応性比の変化は主として反応溶液中におけるMAAの水素結合会合平衡の影響によることが示された。
- 岐阜薬科大学の論文
- 1992-06-30
著者
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近藤 伸一
岐阜薬科大学放射化学研究室
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葛谷 昌之
Matsuyama Univ. Ehime Jpn
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葛谷 昌之
岐阜薬科大学薬品物理化学教室
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野口 章公
Laboratory Of Pharmaceutical Physical Chemistry Gifu Pharmaceutical University
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野口 章公
岐阜薬科大学
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桝井 泰司
岐阜薬科大学
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近藤 伸一
岐阜薬科大学
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