Effects of SrTiO_3 content and Mn doping on dielectric and magnetic properties of BiFeO_3-SrTiO_3 ceramics

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概要

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• Perovskite BiFeO3-SrTiO3 ceramics have been prepared using solid-state reactions. Also, effects of SrTiO3 content on the crystal structure and magnetic properties of a BiFeO3-SrTiO3 system have been studied. Single-phase perovskite BiFeO3-SrTiO3 ceramics have been fabricated/ Pure BiFeO3 ceramics contain a small amount of a second phase, such as Bi36Fe2O57 in perovskite BiFeO3. The crystallographic symmetry of BiFeO3-SrTiO3 changes from rhombohedral to cubic when SrTiO3 exceeds 20 mol%. Moreover, Mn doping to BiFeO3-SrTiO3 is very effective in controlling the grain growth and improving the sintered density. In particular, dielectric loss for the resultant ceramics is greatly reduced by Mn doping. The rhombohedrally distorted 0.9BiFeO3-0.1SrTiO3 shows a high Curie temperature (> 750°C) and weak ferromagnetism at 10-300 K.

• 2009-09-01

著者

• SAKAMOTO Wataru

  Division of Nanomaterials Science, EcoTopia Science Institute, Nagoya University

• YOGO Toshinobu

  Division of Nanomaterials Science, EcoTopia Science Institute, Nagoya University

• Yogo Toshinobu

  Division Of Nanomaterials Science Ecotopia Science Institute Nagoya University

• Sakamoto Wataru

  Division Of Applied Biosciences Graduate School Of Agriculture Kyoto University

• Itoh Naoyuki

  Division Of Nanomaterials Science Ecotopia Science Institute Nagoya University

• SHIMURA Tetsuo

  Division of Nanomaterials Science, EcoTopia Science Institute, Nagoya University

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