Temperature Dependence of Nuclear Quadrupole Resonance Frequencies of 121Sb, 123Sb and 35Cl in Solid Antimony Trichloride
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概要
- 論文の詳細を見る
Nuclear quadrupole resonance frequencies of 121Sb, 123Sb, and 35Cl in solid antimony trichloride were measured between 20°K and about 150°K to learn molecular motions and intermolecular forces in the solid. By use of a newly computed eigenvalue table, the quadrupole coupling constant and the asymmetry parameter of 121Sb and 123Sb were calculated. The asymmetry parameter decreases from 0.192 at 20°K to 0.180 at 140°K. The results were interpreted in terms of librational motion and weak intermolecular covalent bonds between Sb and Cl atoms.
- Physical Society of Japanの論文
- 1968-02-05
著者
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Okuma Hideo
Department Of Chemistr Faculty Of Science Osaka University:(present Address) Toshiba Research And De
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Nakamura Nobuo
Department Of Cardiology Seiyu Memorial Hospital
-
Chihara Hideaki
Department Of Chemistr Faculty Of Science Osaka University
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Nakamura Nobuo
Department of Chemistry, Faculty of Science, Osaka University, Toyonaka, Osaka
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Chihara Hideaki
Department of Chemistry, Faculty of Science, Osaka University, Toyonaka, Osaka
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Okuma Hideo
Department of Chemistry, Faculty of Science, Osaka University, Toyonaka, Osaka
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