Refractive Index along the Molecular Long Axis of an Orthorhombic Thiophene/Phenylene Co-oligomer Crystal

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概要

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• We have determined a refractive index along the crystal long axis of an orthorhombic thiophene/phenylene co-oligomer (TPCO) crystal. From the space group symmetry of the crystal, the three crystallographic axes are identical to the principal axes of the refractive indices. We estimated the index to be 3.76 on the basis of the mode intervals of the equally-spaced longitudinal multimode laser oscillation which is highly polarized along the crystal long axis (i.e., the $a$-axis). This index is much larger than those associated with the other axes. These experimental indices were compared to the semiempirically calculated ones, in qualitatively good agreement with them.

• 2009-04-25

著者

• Yamao Takeshi

  Department Of Electronics And Information Science Faculty Of Engineering And Design Kyoto Institute

• Taniguchi Yuki

  Department Of Chemical Science And Technology Faculty Of Engineering Kyushu University

• Hotta Shu

  Department Of Macromolecular Science And Engineering Graduate School Of Science And Technology Kyoto

• Okuda Yuki

  Department Of Biotechnology And Life Science Faculty Of Engineering Tokyo University Of Agriculture

• YAMAMOTO Kazunori

  Department of Communications Engineering, Graduate School of Engineering, Osaka University

• Inoue Takeshi

  Department Of Animal Husbandry Faculty Of Agriculture Tohoku University

• Okuda Yuki

  Department of Macromolecular Science and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

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