Freezing of High-Temperature Phase in Vinylidene Fluoride/Trifluoroethylene Copolymer Crystals on Vacuum-Evaporated Metal Surfaces
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概要
- 論文の詳細を見る
Vinylidene fluoride/trifluoroethylene copolymer thin films cast from dilute cyclohexanone solution on vacuum-evaporated Pt, Al, Cu, and Au were annealed at 420 K for 1 h. Transmission electron microscopic observation revealed that the high-temperature phase (HP) of the copolymers was frozen even at room temperature with molecular chains normal to the substrate after the annealing. The maximum lattice mismatch was 3.3% between the (001) plane of the HP of the copolymers and the {111} or {110} plane of the Pt crystals. Coulomb's interaction between the copolymer molecules and metallic atoms is suggested to have an important role in causing such phenomena.
- Japan Society of Applied Physicsの論文
- 2007-12-25
著者
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ITOH Takashi
Department of Applied Chemistry, Graduate School of Engineering, Tohoku University
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FUJIWARA Susumu
Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyo
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Hashimoto Masato
Department Of Applied Physics Tokai University
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Hua Thuy-trang
Department Of Macromolecular Science And Engineering Graduate School Of Science And Technology
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Itoh Takashi
Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Kyoto 606-8585, Japan
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Hou Jian-An
Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Kyoto 606-8585, Japan
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Hua Thuy-Trang
Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Kyoto 606-8585, Japan
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Hashimoto Masato
Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Kyoto 606-8585, Japan
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