Molecular Structures and Percolative Phase Transition in Vinylidene Fluoride-Trifluoroethylene Copolymer Crystals
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概要
- 論文の詳細を見る
Tlaeruaaal atad structtrral properties of' vinylideuae fltroride (VDF)-trifltroroethylene (TrFE)copolyuaaers with VDF unolar contents 1.cetxx'een 57 arad T7 rtaol% ttre exazaained by dif[lerenti;tlscanning caloritaaetry, X-ray analysis, IR and "F NIVIR.. It is f'ound f'rotaa the experitnental re-strlts that VDF seqtrences xvith three or taaore naonoraaers jclay an itnportant role in the phasetransition and/or phase appear?trace. Cotaapttter simtrlation ['or tlae copolytnerization stmggeststhat the copolytaaer chain of 65-70% VDF contains ca. 50% VDF which is inclvrded in the longVDF sequences with tltree or 11101'[111 tnonomers. Tltis f'raction (5O'lX) is flue site-percoltttion threshold f'or the two-dimensional triangular 1;tttice; the transf'oruaaat,ion f'rom the contintrotrs strtrcttrralchange to the first-order plaase transition xvith tlae incr'easing VDF ['r?tction is trnderstood as thepercolative ph?rse transition in the txvo-ditnermsional crystal systena.
- 社団法人日本物理学会の論文
- 1998-01-15
著者
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Itoh T
Department Of Macromolecular Science And Engineering Graduate School Of Science And Technology Kyoto
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ITOH Takashi
Department of Applied Chemistry, Graduate School of Engineering, Tohoku University
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Shibata Hiroyuki
Department of Cardiology, Himeji Cardiovascular Center
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HASHIMOTO Masato
Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyo
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MAEDA Kazuhiko
Tokyo Research Center, Central Glass Ltd.
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TASAKA Shigeru
Department of Materials Science,Faculty of Engineering,Shizuoka University
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Shibata H
Nanoelectronics Research Institute National Institute Of Advanced Industrial Science And Technology
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Shibata H
The Institute Of Physical And Chemical Research (riken)
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Maeda K
Sci. Univ. Tokyo Chiba Jpn
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Maeda K
Tokyo Research Center Central Glass Otd.
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Hashimoto M
Department Of Macromolecular Science And Engineering Graduate School Of Science And Technology Kyoto
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Hashimoto M
Department Of Polymer Science And Engineering Faculty Of Textile Science Kyoto Institute Of Technolo
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Shibata Hiroyuki
Department Of Cardiology Himeji Cardiovascular Center
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Shibata H
Department Of Polymer Science And Engineering Faculty Of Textile Science Kyoto Institute Of Technolo
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Maeda Kazuhiko
Tokyo Research Center Central Glass Otd.
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Tasaka Shigeru
Department Of Material Science Department Of Applied Chemistry Faculty Of Engineering Shizuoka Unive
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Hashimoto Masato
Department Of Applied Physics Tokai University
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