Oxidation by Transition Metal Complexes. VI. Oxidation of Cyclohexenes Catalyzed by Rhodium Complexes
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概要
- 論文の詳細を見る
Rhodium complexes can cause the catalytic oxidation of cyclohexene to give ketone, alcohol, and epoxide. The product distribution is dissimilar to that of the metal-catalyzed decomposition of cyclohexene hydroperoxide(V). Ketone and alcohol are derived from the decomposition of the intermediate hydroperoxide (V) but epoxide is not formed by the oxygen transfer reaction from V. Oxidation of methylcyclohexenes was also studied and discussed in relation to the effect of methyl substituent.
- 公益社団法人 日本化学会の論文
著者
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ITOH Takashi
Department of Applied Chemistry, Graduate School of Engineering, Tohoku University
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Fujiwara Yuzo
Department Of Applied Chemistry Faculty Of Engineering Hiroshima University
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Kaneda Kiyotomi
Department of Chemical Engineering, Faculty of Engineeing Science, Osaka University
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Teranishi Shiichiro
Department of Chemical Engineering, Faculty of Engineeing Science, Osaka University
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