Hydration of Propene over Proton- and Metal Ion-Exchanged Zeolite Catalysts at Atmospheric Pressure.
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概要
- 論文の詳細を見る
The gas-phase hydration of propene over proton-exchanged or metal ion-exchanged zeolites with various Si/Al ratios and structures (such as ZSM-5, mordenite, ferrierite, and Y-type) has been studied. It was found that the catalytic activity of proton-exchanged zeolites for the conversion of propene to 2-propanol did not depend on their framework structure, but showed a volcano-shaped dependence on the Al content, as was observed in the hydration of ethene. On the basis of temperature-programmed desorption experiments of NH<SUB>3</SUB> adsorbed on the zeolites, it was confirmed that the activity is controlled by the acidity of the catalysts. The catalytic activity of metal ion-exchanged Y zeolites increased with an increase in the electronegativity of the metal ion.
- 公益社団法人 日本化学会の論文
著者
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Kagawa Shuichi
Department Of Applied Chemistry Faculty Of Engineering
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MIZUNO Noritaka
Catalysis Research Center, Hokkaido University
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Iwamoto Masakazu
Catalysis Research Center Hokkaido University
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Mori Hiroshi
Department Of Applied Physics Okayama University Of Science
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ShiRouzu Toshihiro
Department of Industrial Chemistry, Faculty of Engineering, Nagasaki University
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