An X-ray crystallographic study on the absolute configuration of dihydroyashabushiketol and the solvent-dependence of its optical rotation.
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概要
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The absolute configuration of dihydroyashabushiketol was established to be <I>S</I> on the basis of the X-ray crystallographic analysis of the 4′,4″-dibromo derivative. In addition, it was found that the sense of the optical rotations of dihydroyashabushiketol and its dibromo derivative is determined by the interaction of their C-5 hydroxyl group with the solvent used for the measurements.
- 公益社団法人 日本化学会の論文
著者
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Ohta Shinji
Department Of Crystalline Materials Science Nagoya University
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Aoki Tadashi
Department Of Anesthesiology St. Marianna University School Of Medicine
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Hirata Toshifumi
Department Of Chemistry Faculty Of Science Hiroshima University
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Suga Takayuki
Department Of Chemistry Facalty Of Science Hiroshima University
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