Stereochemical Studies of Monoterpene Compounds. XIV. The Rotational Conformation of the Acetyl and the Formyl Groups of Monoterpene α,β-Unsaturated Carbonyl Compounds
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概要
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Temperature-dependent circular dichroism measurements in the <I>n</I>−π<SUP>*</SUP> transition enabled us to predict the preferred rotational conformation of the acetyl and the formyl groups of such monoterpene α,β-unsaturated carbonyl compounds as (+)-1-acetyl-4-methylcyclohexene (<B>1</B>), (−)-perillaldehyde (<B>2</B>), (+)-1-acetyl-2,4-dimethyl-cyclohexene (<B>3</B>), and(−)-myrtenal (<B>4</B>).
- 公益社団法人 日本化学会の論文
著者
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Suga Takayuki
Department Of Chemistry Facalty Of Science Hiroshima University
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Shishibori Tsuyoshi
Department of Liberal Arts and Sciences, Faculty of Health Sciences, Kagawa Prefectural College of Health Sciences/Department of Medical Technology, Faculty of Health Sciences, Kagawa Prefectural College of Health Sciences
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Imamura Kiyoshi
Department of Chemistry, Faculty of Science, Hiroshima University
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