An odorless preparative method of sulfides and thiocarboxylic S-esters using 3-(alkylthio)-1,2-benzisothiazole 1,1-dioxide.
スポンサーリンク
概要
- 論文の詳細を見る
It was found that sodium salt of 1,2-benzisothiazole-3(2<I>H</I>)-thione 1,1-dioxide (thiosaccharin) readily reacted with alkyl halide affording 3-(alkylthio)-1,2-benzisothiazole 1,1-dioxide (<B>3</B>). Treatment of <B>3</B> with piperidine produces the corresponding alkanethiol <I>in situ</I> quantitatively and subsequent treatment with various electrophiles gives the corresponding sulfides and thiocarboxylic <I>S</I>-esters in good yields.
- 公益社団法人 日本化学会の論文
著者
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Kinoshita Hideki
Department Of Bioscience And Biotechnology Faculty Of Agriculture Shinshu University:united Graduate
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Inomata Katsuhiko
Department Of Chemical Science Graduate School Of Natural Science And Technology Kanazawa University
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Yamada Hiroyuki
Department Of Anatomy School Of Dentistry Aichi-gakuin University
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Kotake Hiroshi
Department of Chemistry, Faculty of Science, Kanazawa University
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