Selective Mono- and Bis(alkoxycarbonylation)s of Olefins Catalyzed by Palladium in the Presence of Cu(I) or Cu(II) Chloride under Remarkably Mild Conditions. Application to the Synthesis of .GAMMA.-Butyrolactone Derivatives.
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概要
- 論文の詳細を見る
Palladium-catalyzed mono- and bis(alkoxycarbonylation)s of olefins were controlled by the use of copper(II) and copper(1) chloride, respectively, in alcohol under normal pressure of carbon monoxide and oxygen at room temperature without any other additives. 3-Buten-1-ols gave the corresponding γ-butyrolactones and 2-oxotetrahydrofuran-3-acetic acid esters, respectively, in high yields.
- 公益社団法人 日本化学会の論文
著者
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MIYAMOTO Masanori
Department of Chemistry, Faculty of Science, Kanazawa University
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Kinoshita Hideki
Department Of Bioscience And Biotechnology Faculty Of Agriculture Shinshu University:united Graduate
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Inomata Katsuhiko
Department Of Chemical Science Graduate School Of Natural Science And Technology Kanazawa University
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Miyamoto Masanori
Department Of Applied Physics Osaka City University
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Toda Shiho
Department of Chemistry, Faculty of Science, Kanazawa University
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