A convenient method for the synthesis of acyclic ketones. Synthesis of sex pheromone of Douglas Fir Tussock Moth.
スポンサーリンク
概要
- 論文の詳細を見る
(α-Alkyl-α-methylthio)alkyl <I>p</I>-tolyl sulfones derived from the reaction of α-alkylated alkyl <I>p</I>-tolyl sulfones with dimethyl disulfide could be easily hydrolyzed by CuCl<SUB>2</SUB>–SiO<SUB>2</SUB> to give the corresponding ketones in fairly good yields. This method was applied to the synthesis of Douglas Fir Tussock Moth Pheromone.
- 公益社団法人 日本化学会の論文
著者
-
Kinoshita Hideki
Department Of Bioscience And Biotechnology Faculty Of Agriculture Shinshu University:united Graduate
-
Inomata Katsuhiko
Department Of Chemical Science Graduate School Of Natural Science And Technology Kanazawa University
-
Kotake Hiroshi
Department of Chemistry, Faculty of Science, Kanazawa University
-
Murata Yasue
Department of Chemistry, Faculty of Science, Kanazawa University
関連論文
- Control of Enantiofacial Differentiation in the Addition Reaction of Organometallics to a Nitrone in the Presence of an External Chiral Auxiliary
- "Syn-Effect" in the Conversion of (E)-α, β-Unsaturated Esters to the Corresponding β, γ-Unsaturated Esters
- "Syn-Effect"in the Isomerization of (E)-α-Fluorovinylic Sulfones to the Corresponding Allylic Sulfones under Basic Conditions
- SIGNIFICANCE OF CORONARY ARTERY TONE ASSESSED BY CORONARY RESPONSES TO ERGONOVINE AND NITRATE
- Expression and Subcellular Localization of Candida tropicalis Catalase in Catalase Gene Disruptants of Saccharomyces cerevisiae
- "Syn-Effect" in the Desilylation Reaction of γ-Silylated Allylic and Vinylic Sulfones
- Asymmetric Bis(alkoxycarbonylation) Reaction of Terminal Olfins Catalyzed by Palladium in the Presence of Copper(I) Triflate and a Chiral Bioxazoline Ligand
- Asymmetric Bis(alkoxycarbonylation) Reaction of Homoallylic Alcohols Catalyzed by Palladium in the Presence of Cu(I) Triflate Using the Chiral Bioxazoline Ligand
- TREATMENT OF TORSADE DE POINTES WITH INTRAVENOUS MAGNESIUM IN IDIOPATHIC LONG QT SYNDROME
- An Efficient Method for the Conversion of 2-Bromo-5-tosylpyrroles to the Corresponding 5-Tosylpyrrolinones as the D-Ring of Phycocyanobilin Derivatives
- Total Syntheses of Phycocyanobilin Derivatives Bearing a Modified A-Ring toward the Structure/Function Analysis of Phytochrome
- Efficient Synthesis of B- and C-Rings Components of Phycobilin Derivatives for Structure/Function Analysis of Phytochrome
- An Efficient Method to Construct the A,B-Rings Component toward Total Syntheses of Phycocyanobilin and Its Derivative as a Photoprobe
- Total Syntheses of (±)-Phycocyanobilin and Its Derivatives Bearing a Photoreactive Group at D-ring
- Syntheses of 3,4-Disubstituted 2-Tosylpyrroles and 5-Tosyl-1,5-dihydro-2H-pyrrol-2-ones Starting from Ethyl 3,4-Disubstituted 2-Pyrrolecarboxylates
- Convenient and Regioselective Syntheses of 3, 4-Disubsutituted Δ^3-Pyrrolin-2-one Derivatives Starting from 2-Tosyl-3, 4-Disubstituted Pyrroles
- Catalytic Asymmetric 1, 3-Dipolar Cycloaddition of Nitrile Oxides to an Achiral Allyl Alcohol Utilizing Diisopropyl Tartrate as a Chiral Auxiliary
- "Syn-Effect" in the Desulfonylation Reaction of a, a-Dialkylated (E)-Allylic Sulfones
- -P30-MECHANISMS FOR INTRACELLULAR CALCIUM OSCILLATION RELATED TO CALCIUM OVERLOAD IN CARDIAC CELL : Electrophysiology : FREE COMMUNICATIONS(III) : PROCEEDINGS OF THE 53th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY
- Catalytic Asymmetric Addition of Dialkylzinc to 3,4-Dihydroisoquinoline N-Oxides Utilizing Tartaric Acid Ester as a Chiral Auxiliary
- Catalytic Asymmetric Addition Reaction of Dialkylzinc to Nitrone Utilizing Tartaric Acid Ester as a Chiral Auxiliary
- Competitive Amino Acid Transport between L-Tryptophan and Other Amino Acids in Schizophyllum commune
- A New Method for the Preparation of A- and D-Rings of Phycocyanobilin Using Mucochloric Acid as a Starting Material
- A New Aerobic Oxidation System Using Pd-Cu Catalysts in the Presence of CO
- A New and Convenient Wittig-type Reaction for the Preparation of Pyrromethenone Derivative
- A New Synthetic Method for the Preparation of α,β-Didehydroamino Acid Derivatives by Means of a Witting-Type Reaction, Syntheses of (2S,4S)- and (2R,4R)-4-Hydroxyprolines
- Asymmetric Addition of Reformatsky-Type Reagent to Imines Utilizing Diisopropyl Tartrate as a Chiral Auxiliary
- Efficient Construction of A, B-Rings Component for Syntheses of Phycocyanobilin and Its Derivative
- Preparation of As-Deposited 80 K-Phase Bi-Sr-Ca-Cu-O Films by RF Mgnetron Sputtering
- The First Enantioselective Hetero Diels-Alder Reaction of Nitroso Compound Utilizing Tartaric Acid Ester as a Chiral Auxiliary
- Catalytic Asymmetric 1,3-Dipolar Cycloaddition of a Nitrone Bearing a Bulky Amide Moiety to γ-Substituted Allylic Alcohols
- Asymmetric 1,3-Dipolar Cycloaddition of Nitrile Oxides to γ-Substituted Allylic Alcohols
- Coordination Asymmetry of a Dinuclear Copper(II) Complex: Synthesis, Structure, and Magnetism
- A Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Nitrones to Allyl Alcohol
- Controlled Synthesis of C/D-Ring Components of Phycobilin Derivatives Bearing a Photoreactive Group at D-Ring
- Homologation Reaction of γ-Silicon Substituted Allylic Alcohols Using Organoaluminium Reagents and Diiodomethane
- Evaluation of Peroxisomal Heme in Yeast
- A New and Convenient Method for the Synthesis of Dehydroamino Acids Starting from Ethyl N-Boc- and N-Z-α-Tosylglycinates and Various Nitro Compounds
- Rearrangement of Tosyl Group of 3,4-Disubstituted 2-Tosylpyrroles under Mild Acidic Conditions
- A Highly Efficient Method for the Preparation of the A/B-Ring Component of Phycobilin Derivatives Starting from Bilirubin
- Palladium-Catalyzed Carbonylation of Homoallylic Amine Derivatives in the Presence of a Copper Co-catalyst
- Asymmetric 1,3-Dipolar Cycloaddition of Nitrile Oxides Generated in situ by Direct Oxidation of Aldoximes
- Enantio- and Diastereoselective Synthesis of Isoxazolidines by Asymmetric 1, 3-Dipolar Cycloaddition of Nitrones
- Enantioselective Synthesis of 2-Isoxazolines via Asymmetric 1,3-Dipolar Cycloaddition of Nitrile Oxide to Achiral Allyl Alcohol
- Synthesis of Silicon Substituted Cyclopropylmethyl Alcohols in Optically Active Form via Asymmetric Simmons-Smith Reaction of γ-Silicon Substituted Allylic Alcohols
- A New Synthetic Method for Dipeptides Containing α, β-Didehydroamino Acids Utilizing an α-Tosylglycine Residue
- A general synthetic method for 1-substituted 1,4-dihydro-3(2H)-isoquinolinones.
- A synthetic method for N-benzyloxycarbonyl hydroxy amino acid t-butyl esters.
- Synthesis of a peptide lactone, N-(3-hydroxypicolinyl)-threonyl-D-leucyl-prolylsarcosyl-leucyl-alanyl-alanine threonine lactone.
- The reactions of 2-fluoro-1,3,5-trinitrobenzene (FTNB) as a new condensing reagent.
- Preparation and Diels-Alder reactions of 3-substituted 3-sulfolenes.
- A new peptide synthesis using 2-fluoro-1,3,5-trinitrobenzene. Syntheses of thyrotropin releasing hormone and leucine-enkephalin.
- Halogenation of alkyl p-tolyl sulfones with carbon tetrahalides. Application to the synthesis of aromatic ketones.
- A new and effective synthetic method for the preparation of the esters, peptides, and lactones using 3-(5-nitro-2-oxo-1,2-dihydro-1-pyridyl)-1,2-benzisothiazole 1,1-dioxide. Synthesis of (.+-.)-(E)-8-dodecen-11-olide, recifeiolide.
- Convenient methods for the preparation of vinylic and allylic sulfones from alkenes, haloalkanes, and aldehydes. Stereochemistry of the conversion of vinylic sulfones to the corresponding allylic sulfones.
- Selective Mono- and Bis(alkoxycarbonylation)s of Olefins Catalyzed by Palladium in the Presence of Cu(I) or Cu(II) Chloride under Remarkably Mild Conditions. Application to the Synthesis of .GAMMA.-Butyrolactone Derivatives.
- Synthesis of 3-acylfurans using 3-(phenylthio)propanal dimethyl acetal as a new synthon. Syntheses of ipomeanine and isoegomaketone.
- An odorless preparative method of sulfides and thiocarboxylic S-esters using 3-(alkylthio)-1,2-benzisothiazole 1,1-dioxide.
- The Resolution of N-Benzyloxycarbonyl-DL-amino Acids Using Ephedrine
- A convenient method for the synthesis of acyclic ketones. Synthesis of sex pheromone of Douglas Fir Tussock Moth.
- Quaternary ammonium periodate as a new oxidizing agent.