A new and effective synthetic method for the preparation of the esters, peptides, and lactones using 3-(5-nitro-2-oxo-1,2-dihydro-1-pyridyl)-1,2-benzisothiazole 1,1-dioxide. Synthesis of (.+-.)-(E)-8-dodecen-11-olide, recifeiolide.
スポンサーリンク
概要
- 論文の詳細を見る
3-(5-Nitro-2-oxo-1,2-dihydro-1-pyridyl)-1,2-benzisothiazole 1,1-dioxide(BID-NPy), readily prepared from 3-chloro-1,2-benzisothiazole 1,1-dioxide and 5-nitro-2-pyridone, proved to be a very useful condensing reagent. A variety of esters, dipeptides, and lactones were obtained in excellent yields. Furthermore, BID-NPy was successfully employed for the lactonization step in a new synthesis of a naturally occurring (±)-(<I>E</I>)-8-dodecen-11-olide, recifeiolide.
- 公益社団法人 日本化学会の論文
著者
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Kinoshita Hideki
Department Of Bioscience And Biotechnology Faculty Of Agriculture Shinshu University:united Graduate
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Inomata Katsuhiko
Department Of Chemical Science Graduate School Of Natural Science And Technology Kanazawa University
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Ahmed Alauddin
Department Of Chemistry Faculty Of Science Kanazawa University
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Kotake Hiroshi
Department of Chemistry, Faculty of Science, Kanazawa University
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Fukuda Hirohiko
Department of Chemistry, Faculty of Science, Kanazawa University
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Taniguchi Nagahiro
Department of Chemistry, Faculty of Science, Kanazawa University
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