New amino-protective reagents for t-butoxycarbonylation and benzyloxycarbonylation of amines and amino acids.
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概要
- 論文の詳細を見る
New amino-protective reagents for <I>t</I>-butoxycarbonylation and benzyloxycarbonylation of amines and amino acids have been developed. <I>t</I>-Butyl 2-pyridyl carbonate and <I>t</I>-butyl <I>S</I>-(2-pyridyl) thiocarbonate react cleanly with various amines and amino acids to afford <I>N</I>-Boc amines and <I>N</I>-Boc amino acids in high yields. Benzyl 2-pyridyl carbonate and <I>O</I>-benzyl <I>S</I>-(2-pyridyl) thiocarbonate are also found to be very effective in the benzyloxycarbonylation of amino acids.
- 公益社団法人 日本化学会の論文
著者
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Kim Sunggak
Department Of Chemistry Korea Advanced Institute Of Science And Technology
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Lee Jae
Department Of Acupuncture & Moxibustion College Of Oriental Medicine
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Yi Kyu
Department of Chemistry, Korea Advanced Institute of Science and Technology
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Lee Jae
Department of Chemistry, Korea Advanced Institute of Science and Technology
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