Anodic oxidation of cyclohexanone on lead dioxide electrode in aqueous sulfuric acid solution.

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概要

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• The electrolytic behavior of cyclohexanone was examined by potentiometry with rotating disk electrode as well as by product analyses. The reaction was activation controlled and the reaction orders were first with respect to cyclohexanone and zero for proton. Cyclohexanone reacted by approximately 6 electrons to give adipic acid mainly which accumulated proportionally to the electricity consumed. Changes in temperature, proton concentration, and current density resulted in only minor effects on the reaction. In neutral solution, however, the oxidation was suppressed and oxygen evolution dominated. Other electrode materials such as Pt, graphite, RuO<SUB>2</SUB>, and PtO<SUB>2</SUB> were inactive. The chemical oxidation with PbO<SUB>2</SUB> itself did not occur. From these facts, reaction mechanism was discussed.

• 公益社団法人 日本化学会の論文

著者

• Kunai Atsutaka

  Department Of Applied Chemistry Graduate School Of Engineering Hiroshima University

• Sasaki Kazuo

  Department Of Applied Chemistry Faculty Of Engineering Hiroshima University

• SASAKI Kazuo

  Department of Applied Chemistry, Faculty of Engineering, Hiroshima University

• Hatoh Kazuhito

  Department of Applied Chemistry, Faculty of Engineering, Hiroshima University

• Hirano Yoshinobu

  Department of Applied Chemistry, Faculty of Engineering, Hiroshima University

• Harada Junji

  Department of Applied Chemistry, Faculty of Engineering, Hiroshima University

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