Molecular structure of trimethylphosphine-borane as determined from electron diffraction and microwave spectroscopic data.
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概要
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The molecular structure of trimethylphosphine–borane has been determined from gas electron diffraction and spectroscopic data. The molecular parameters and their uncertainties are <I>r</I><SUB>g</SUB>(B–H)=1.225±0.011 Å, <I>r</I><SUB>g</SUB>(P–B)=1.899±0.006 Å, <I>r</I><SUB>g</SUB>(C–P)=1.815±0.003 Å, <I>r</I><SUB>g</SUB>(C–H)=1.103±0.002 Å, ∠HBH=108.6±0.6°, and ∠CPC=104.6±0.3°. The P–B distance of this complex is about 0.04 Å shorter than those of trimethylphosphine–boron trihalides.
- 公益社団法人 日本化学会の論文
著者
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Iijima Kinya
Department Of Chemistry Faculty Of Science Shizuoka University
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Shibata Shuzo
Department Of Chemistry Faculty Of Science Shizuoka University
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Nishikawa Takashi
Department of Biotechnology, Graduate School of Engineering, Osaka University
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Nishikawa Takashi
Department of Chemistry, Faculty of Science, Shizuoka University
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Hakamata Yumi
Department of Chemistry, Faculty of Science, Shizuoka University
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Iijima Kinya
Department of Applied Chemistry, Faculty of Engineering, Yamanashi University
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