The application of diarylamine compounds in analytical chemistry. 1. Fluorescence reactions among 4-(4-methyl-2-quinolyl)aminosalicylic acid, cobalt(II) and hydrogen peroxide, and the fluorimetry of cobalt(II) by using its fluorescence reaction.
スポンサーリンク
概要
- 論文の詳細を見る
The fluorescence reactions among 4-(4-methyl-2-quinolyl)aminosalicylic acid (MQAS) as a diarylamine compound, hydrogen peroxide as an oxidizing agent, and various metal ions such as cobalt(II) were spectrolluorometrically investigated in the presence or in the absence of various surfactants. The MQAS–hydrogen peroxide solution in the presence of trimethylstearylammonium chloride (STAC) as a cationic surfactant was catalytically converted to a fluorescence product by the coexistence of trace amounts of cobalt(II), and its relative fluorescence intensity at 400 nm in the fluorescence reaction product was proportional to the cobalt(II) concentrations. Moreover, a highly selective and sensitive fluorimetric method for the determination of cobalt(II) using MQAS and hydrogen peroxide in the presence of STAC in basic media was proposed. The calibration graph was linear in the range of 0–45 ng cobalt(II) per 10 cm<SUP>3</SUP> at an emission wavelength of 400 nm, with an excitation wavelength of 320 nm.
- 公益社団法人 日本化学会の論文
著者
-
Akagi Masao
Osaka University Of Pharmaceutical Sciences
-
MORI Itsuo
Osaka College of Pharmacy
-
Kato Keiji
Osaka University of Pharmaceutical Sciences
-
Toyoda Minako
Osaka University of Pharmaceutical Sciences
-
Fujita Yoshikazu
Osaka College of Pharmaceutical Sciences
関連論文
- Fluorophotometric Determination of Hydrogen Peroxide and Other Reactive Oxygen Species with Fluorescein Hydrazide (FH) and Its Crystal Structure
- EFFECTS OF CHIRAL MODIFICATION ON THE HELICAL STRUCTURE OF ADENYLYL(3'-5')ADENYLYL(3'-5')ADENOSINE(Chiral Homogeneity and D-Amino Acids, International Symposium on Origins of Life and Astrobiology)
- Efficient and Homochiral Selective Oligomerization of Racemic Ribonucleotides on Mineral Surface
- Design and Racemic Synthesis of Conformationally Restricted Carbocyclic Pyrimidine Nucleoside Analogs Based on the Structure of the L-Nucleoside Residue in Heterochiral DNA
- SPECTROPHOTOMETRIC DETERMINATION OF VANADIUM WITH GALLEIN AND SODIUM LAURYLSULFATE
- A Practical Synthesis of L-Ribose
- Spectrophotometric Determination of Spermine and Related Compounds Using o-Hydroxyhydroquinonephthalein and Manganese(II)
- SPECTROPHOTOMETRIC DETERMINATION OF BERBERINE CHLORIDE IN PHARMACEUTICAL PREPARATIONS
- SPECTROPHOTOMETRIC DETERMINATION OF GERMANIUM(IV) USING ο-HYDROXYHYDROQUINONEPHTHALEIN AND CETYLPYRIDINIUM CHLORIDE
- COLOR REACTION BETWEEN POLYAMINES AND ο-HYDROXYHYDROQUINONEPHTHALEIN-COPPER(II) COMPLEX