Formation of 1,2-Dioxanes by the Use of Tris(2,4-pentanedionato)-manganese(III) or Manganese(III) Acetate.
スポンサーリンク
概要
- 論文の詳細を見る
The reactions of 1,1-diphenylethene, 1,1-bis(4-chlorophenyl)ethene, 1,1-bis(4-methoxyphenyl)ethene, 1,1-bis(4-methylphenyl)ethene, 1,1-bis(4-fluorophenyl)ethene, styrene, 1-octene, cyclohexene, and cyclooctene with tris(2,4-pentanedionato)manganese(III) ([Mn(acac)<SUB>3</SUB>]) in acetic acid at room temperature give 4-acetyl-3-methyl-1,2-dioxan-3-ol in 8–92% yields, together with 3-acetyl-4-hydroxy-3-hexene-2,5-dione. The similar reactions of 1,1-diphenylethene with 2,4-pentanedione, 3-methyl-2,4-pentanedione, 3-ethyl-2,4-pentanedione, 1-phenyl-1,3-butanedione, acetoacetanilide, and 1,3-cyclohexanedione in the presence of manganese(III) acetate also give the corresponding cyclic peroxide in good to moderate yields. The mechanisms of manganese(III)-induced 1,2-dioxane ring formation and concomitant radical side reaction are discussed.
- 公益社団法人 日本化学会の論文
著者
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Korp James
Department Of Chemistry University Of Huston
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Kurosawa Kazu
Department Of Chemistry Faculty Of Science Kumamoto University
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Yamada Takashi
Department Of Animal Science Graduate School Of Agricultural Science Kobe University
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Nishino Hiroshi
Department Of Applied Chemistry National Defense Academy
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Tategami Shin-ichi
Department of Chemistry, Faculty of Science, Kumamoto University
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