The formation of a propellane by the oxidation of biphenylene with manganese(III) acetate.
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概要
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The reaction of biphenylene with manganese (III) acetate gave 2-acetoxybiphenylene, 2-formylbiphenylene, 2-(acetoxymethyl)biphenylene, and 7-oxa-10,11-benzotricyclo[4.3.2.0]undeca-2,4,10-trien-8-one. The reaction pathways are discussed.
- 公益社団法人 日本化学会の論文
著者
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Kurosawa Kazu
Department Of Chemistry Faculty Of Science Kumamoto University
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McOmie John
School of Chemistry, The University
関連論文
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- The .ALPHA.-chlorination of aryl ketones with manganese(III) acetate in the presence of chloride ion.
- The oxidation of biphenylene and its derivatives with Mn(OAc)3 and Pb(OAc)4.
- Reactions of 1,1-Disubstituted Alkenes with Acetoacetamides and Molecular Oxygen in the Presence of Manganese(III) Acetate.
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- The reaction of acetophenones with manganese(III) acetate.
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- Benzocyclobutenes. Part 8. Geometrical isomerism of arylhydrazones of benzocyclobutene-1,2-dione.
- Reactions of .ALPHA.,.BETA.-unsaturated carboxylates, malonates and phenylacetates with manganese(III) acetate in the presence of chloride ions.
- The Reactions of 2-Hydroxystilbenes with Lead Tetraacetate and Manganic Acetate
- The reactions of 1,3-indandiones and 1,3(2H)-phenalenediones with lead tetraacetate.
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- Reaction of secondary aromatic amines with manganese(III) acetate.
- Reactions of aryl ketones and coumarins with iodine(III) tris(trifluoroacetate).