The reactions of 1,3-indandiones and 1,3(2H)-phenalenediones with lead tetraacetate.
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概要
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The reaction of 1,3-indandione with lead tetraacetate gave phthalic anhydride and 2,2-diacetoxy-1,3-indandione. The reaction of 2,2-dihydroxy-1,3-indandione gave phthalic anhydride. The reactions of 1,3(2<I>H</I>)-phenalenedione and 2,3-dihydroxy-1-phenalenone yielded acenaphthenequinone and 1,8-naphthalenedicarboxylic anhydride. The reactions of acenaphthenequinone and 2,2-dihydroxy-1,3-phenalenedione gave 1,8-naphthalenedicarboxylic anhydride with higher yields. The reactions of [2-<SUP>14</SUP><I>C</I>]-labeled compounds showed that the middle carbon atom was lost.
- 公益社団法人 日本化学会の論文
著者
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Kurosawa Kazu
Department Of Chemistry Faculty Of Science Kumamoto University
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Ezoe Keiichi
Department of Chemistry, Faculty of Science, Kumamoto University
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